Outer approximation is a basic approach for solving Mixed Integer Nonlinear Programming (MINLP) models suggested by Duran and Grossmann (1986) . Based on principles of decomposition, outer-approximation and relaxation, the proposed algorithm effectively exploits the structure of the original problems. The new problems consist of solving an alternating finite sequence of nonlinear programming subproblems and relaxed versions of a mixed-integer linear master program.
Upper Bonding Subproblem
Convergence and Optimality
To obtain a global optimum, the original MINLP should be convex, which means that all the constraints and objective function should be convex. The proposed algorithm can be applied to non-convex problems, but there is no guarantee that the solution obtained by the algorithm is a global one.
A Numerical Example
 Duran M A, Grossmann I E. An outer-approximation algorithm for a class of mixed-integer nonlinear programs[J]. Mathematical programming, 1986, 36(3): 307-339.  Fletcher R, Leyffer S. Solving mixed integer nonlinear programs by outer approximation[J]. Mathematical programming, 1994, 66(1-3): 327-349.